低共熔溶剂取代危化品的应用进展

doi:10.12034/j.issn.1009-606X.20180127

摘要/Abstract

摘要： 危化品在工业生产应用中存在着巨大的危险性和危害性，低共熔溶剂作为一种安全、环保、价格低廉、更具工业化潜力的新型离子液体受到越来越多的关注. 根据低共熔溶剂取代的危化品种类，分析了低共熔溶剂在金属催化剂制备、生物催化转化、气体分离与吸收、有机合成和电化学等反应中的作用. 采用绿色化学原则和葛兰素史克溶剂选择指南等对低共熔溶剂应用中出现的问题和存在的难点做出了展望.

关键词: 低共熔溶剂, 危化品, 聚合反应, 生物转化, 气体分离

Abstract: Hazardous chemicals applied in industry suffer great risks and would result in potential danger. As a new type of ionic liquids, deep eutectic solvents (DES) are known for safety, environments friendly, and inexpensive. DES have attracted more and more attentions, and been considered as a promising substitute of hazardous chemicals. This statement was mainly devoted to introduce the definition of principles of green chemistry and GSK solvent selection guide, and apply them to the safety assessment of chemical industry with Deep Eutectic Solvents replacing of hazardous chemicals. In the passage, the harm from hazardous chemicals in chemical industry was firstly reviewed. Based on this, the advantage of DES was illustrated, and it was a promising replacement of hazardous chemicals. The definition, classification, and the properties of DES were descripted. The application progress of DES in preparing metal-catalysts, biomass transformation, gas separation, polymerization, and electrochemical to substitute for hazardous chemicals were reviewed. The behaviors of DESs in replacement of hazardous chemicals were studied according to the Principles of green chemistry and GSK solvent selection guide. As solvent, DES can replace inflammable and highly toxic organic solvents, such as toluene and benzene, which were dangerous to environment. As catalyst, DES can enhance the selectivity and efficiency. As reactant, DES can avoid the usage of toxic reactant. Moreover, the problems and difficulties in research and applications were investigated, and then the prospective application of DES was offered.

Key words: deep eutectic solvents, hazardous chemicals, polymerization, biomass transformation, gas separation

任红威连少翰王雪张优张金峰段二红. 低共熔溶剂取代危化品的应用进展[J]. 过程工程学报, 2018, 18(S1): 1-13.

Hongwei REN Shaohan LIAN Xue WANG You ZHANG Jinfeng ZHANG Erhong DUAN. Progress of replacement of hazardous chemicals used in chemical industry with deep eutectic solvents[J]. Chin. J. Process Eng., 2018, 18(S1): 1-13.

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