普鲁士蓝钠离子电池正极材料高收率合成过程及性能

doi:10.12034/j.issn.1009-606X.217403

过程工程学报 ›› 2018, Vol. 18 ›› Issue (4): 809-814.DOI: 10.12034/j.issn.1009-606X.217403

普鲁士蓝钠离子电池正极材料高收率合成过程及性能

孙李琪1,2，严小敏1,2，唐婉1,2，何雨石1,2，马紫峰1,2，廖小珍1,2*

1. 上海交通大学化学工程系，上海 200240
2. 上海电化学能源器件工程技术研究中心，上海 200240

收稿日期:2017-11-29 修回日期:2018-01-19 出版日期:2018-08-22 发布日期:2018-08-15
通讯作者: 廖小珍 liaoxz@sjtu.edu.cn
基金资助:
国家自然科学基金面上项目;上海市自然科学基金

High yield synthesis process and performance of prussian blue cathode materials for sodium ion batteries

Liqi SUN1,2, Xiaomin YAN1,2, Wan TANG1,2, Yushi HE1,2, Zifeng MA1,2, Xiaozhen LIAO1,2*

1. School of Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China
2. Shanghai Electrochemical Energy Devices Research Center, Shanghai 200240, China

Received:2017-11-29 Revised:2018-01-19 Online:2018-08-22 Published:2018-08-15

摘要/Abstract

摘要： 用高氯酸盐前躯体制备普鲁士蓝(PB)材料，考察了合成过程中前驱体成分、溶液温度、钠盐添加量及杂质含量对材料性能的影响. 结果表明，氯化亚铁作铁源时，不清洗的普鲁士蓝产物中含NaCl杂质，电化学性能明显低于经多次清洗的产物；高氯酸亚铁作铁源时，不清洗直接收集的普鲁士蓝产物初始放电容量略低于清洗产物，但长期循环稳定性更好，免清洗工艺可明显提高普鲁士蓝材料的收率，少量高氯酸钠杂质存在提高了材料的循环性能.

关键词: 钠离子电池, 正极材料, 普鲁士蓝

Abstract: A high yield preparation method for prussian blue (PB) by using perchlorate precursors was explored. The influence of compositions of the precursor solution, preparation temperature, sodium salt addition and impurities in the final products on the electrochemical properties of final PB products were investigated. The results showed that the existence of impurities lead to a slight decrease of specific capacity. For PB material prepared using FeCl2 precursor, electrochemical performance of the unwashed sample was obvious inferior to that of the washed sample due to the existence of NaCl impurity. On the other hand, for the PB material prepared by using Fe(ClO4)2 precursor, initial discharge capacity of PB product without being clean washed was slightly lower than being washed but showed better cycling stability due to the existence of small amount of NaClO4 impurity. The unwash synthesis route leads to a high yield of PB product.

Key words: sodium ion battery, cathode material, plussian blue

孙李琪严小敏唐婉何雨石马紫峰廖小珍. 普鲁士蓝钠离子电池正极材料高收率合成过程及性能[J]. 过程工程学报, 2018, 18(4): 809-814.

Liqi SUN Xiaomin YAN Wan TANG Yushi HE Zifeng MA Xiaozhen LIAO. High yield synthesis process and performance of prussian blue cathode materials for sodium ion batteries[J]. Chin. J. Process Eng., 2018, 18(4): 809-814.

参考文献

[1]Il Park S, Gocheva I.Okada S,et al..Electrochemical Properties of NaTi2(PO4)(3) Anode for Rechargeable Aqueous Sodium-ion Batteries[J].Journal of the Electrochemical Society, 2011, 158(10):A1067-A1070
[2]Kawabe Y, Yabuuchi N.Kajiyama M,et al..Synthesis and Electrode Performance of Carbon Coated Na2FePO4F for Rechargeable Na Batteries[J].Electrochemistry Communications, 2011, 13(11):1225-1228
[3]Komaba S, Murata W.Ishikawa T,et al..Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-carbon Electrodes and Application to Na-ion Batteries[J].Advanced Functional Materials, 2011, 21(20):3859-3867
[4]Komaba S, Takei C.Nakayama T,et al..Electrochemical Intercalation Activity of Layered NaCrO2 vs. LiCrO2[J].Electrochemistry Communications, 2010, 12(3):355-358
[5]Lu Y.H.,Wang L,Cheng J. G.,et al..Prussian blue: a New Framework of Electrode Materials for Sodium Batteries[J].Chemical Communications, 2012, 48(52):6544-6546
[6]Qian J.F.,Zhou M,Cao Y. L.,et al..Nanosized Na4Fe(CN)6C Composite as a Low-cost and High-rate Cathode Material for Sodium-ion Batteries[J].Advanced Energy Materials, 2012, 2(4):410-414
[7]Komabaa S, Nakayamaa T.Ogataa A.Electrochemically Reversible Sodium Intercalation of Layered NaNi0.5Mn0.5O2 and NaCrO2[J].The Electrochemical Society, 2009, 16(42):43-45
[8]Mu L.Q.,Xu SY.,Li Y. M.,et al..Prototype Sodium-ion Batteries Using an Air-stable and CoNi-free O-3-layered Metal Oxide Cathode[J].Advanced Materials, 2015, 27(43):6928-+
[9]Zhang Q.Wang W,Wang Y. J.,et al..Controllable Construction of 3D-skeleton-carbon Coated Na3V2(PO4)(3) for High-Performance Sodium ion Battery Cathode[J].Nano Energy, 2016, 20:11-19
[10]Yang Y.Liu ES.,Yan X. M.,et al..Influence of Structural Imperfection on Electrochemical Behavior of Prussian Blue Cathode Materials for Sodium ion Batteries[J].Journal Of the Electrochemical Society,2016, 163(9):A2117-A2123
[11]Chen J.Ding ZY.,Wang C.,et al..Black Anatase Titania with Ultrafast Sodium-storage Performances Stimulated by Oxygen Vacancies[J].Acs Applied Materials & Interfaces, 2016, 8(14):9142-9151
[12] Wessells C.D., Huggins R. A., Cui Y., et al..Copper Hexacyanoferrate Battery Electrodes with Long Cycle Life and High Power [J].Nature Communications, 2011（2）.
[13]杨汉西，钱江锋.水溶液钠离子电池及其关键材料的研究进展[J].无机材料学报, 2013, 28(11):1165-
[14]You Y, Wu X.L.,Yin YX.,et al..High-quality Prussian Blue Crystals as Superior Cathode Materials for Room-temperature Sodium-ion Batteries[J].Energy & Environmental Science, 2014, 7(5):1643-1647
[15]Yang D.Z.,Liao XZ,Huang B. W.,et al. A Na4Fe(CN)6NaCl Solid Solution Cathode Material with an Enhanced Electrochemical Performance for Sodium ion Batteries[J].Journal of Material Chemistry A, 2013, 1(42):13417-13421
[16]Yang D.Z.,Xu J,Liao XZ.,et al. Structure Optimization of Prussian Blue Analogue Cathode Materials for Advanced Sodium ion Batteries[J].Chemical Communication., 2014, 50(87):13377-13380
[17]Yan X.M.,Yang Y,Liu E. S.,et al..Improved Cycling Performance of Prussian Blue Cathode for Sodium ion Batteries by Controlling Operation Voltage Range[J].Electrochemica Acta, 2017, 225:235-242

普鲁士蓝钠离子电池正极材料高收率合成过程及性能

High yield synthesis process and performance of prussian blue cathode materials for sodium ion batteries

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

[1]	蔡铖张海燕王英付海阔黄玲唐仁衡肖方明. 锂离子电池高镍三元正极材料LiNi_0.8Co_0.1Mn_0.1O₂的性能研究[J]. 过程工程学报, 2022, 22(6): 754-763.
[2]	杨馨蓉车海英杨轲潘朝梁廖小珍马紫峰. 硬碳负极材料的热稳定性及其钠离子电池安全性能评测[J]. 过程工程学报, 2022, 22(4): 552-560.
[3]	靳佳魏进平周震. 5 V尖晶石型无钴LiNi_0.5Mn_1.5O₄正极材料进展综述[J]. 过程工程学报, 2022, 22(4): 421-437.
[4]	朱多银金志浩李文丽汪前雨武荣成崔彦斌. PB/ITO-PET柔性电致变色薄膜制备及性能研究[J]. 过程工程学报, 2022, 22(2): 176-185.
[5]	孙阳王红车海英廖小珍李林森崔桂嘉杨为民马紫峰. ZrO₂包覆对层状氧化物正极材料储钠性能的改善[J]. 过程工程学报, 2022, 22(1): 72-78.
[6]	张贺杰陈兴邹兴刘文科郑诗礼张懿李平. 废旧锂离子电池正极材料除铝技术研究进展[J]. 过程工程学报, 2020, 20(5): 503-509.
[7]	董虎林包海萍汪浩彭建洪. 磷酸钒锂正极材料掺杂改性研究进展[J]. 过程工程学报, 2019, 19(3): 483-491.
[8]	郑双双刘艳侠马立彬. 高能量密度锂离子电池LiNi0.8Co0.15Al0.05O2正极材料改性的研究进展[J]. 过程工程学报, 2018, 18(2): 225-231.
[9]	李妍汪小平张维民何雨石马紫峰. 铷掺杂三元正极材料Li1-xRbxNi0.4Co0.2Mn0.4O2的制备及其电化学性能[J]. 过程工程学报, 2018, 18(2): 422-426.
[10]	国海鹏贾梦秋廖煜炤翟中楠. 锂离子电池正极材料LiNi1/2Co1/6Mn1/3O2的制备与性能[J]. , 2008, 8(4): 808-813.
[11]	刘涛;杜荣斌;姜效军. SnO2对尖晶石LiMn2O4电极材料的改性[J]. , 2007, 7(5): 1045-1049.
[12]	王希敏;王先友;易四勇;曹俊琪. 层状锂离子电池正极材料LiNi0.8Co0.1Mn0.1O2的制备及性能[J]. , 2007, 7(4): 817-821.
[13]	刘丽英;田彦文;翟玉春;徐茶清. 锂钒氧化物的液相法合成及电化学性能[J]. , 2006, 6(4): 670-673.
[14]	李辉;杨尚林;翟玉春;田彦文. 锂离子电池正极材料LiNi0.8M0.2O2的制备[J]. , 2002, 2(6): 0-0.
[15]	文明芬;翟玉春;陈廉;等. 快淬Zr0.9Ti0.1(Ni,Co,Mn,V)2.1贮氢合金的结构与性能[J]. , 2001, 1(4): 0-0.