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过程工程学报 ›› 2019, Vol. 19 ›› Issue (2): 393-399.DOI: 10.12034/j.issn.1009-606X.218204

• 材料工程 • 上一篇    下一篇

MgxTiAlFeNiCr (x=0.6~2.0)高熵合金微结构演变及耐蚀性

斯庭智*， 刘清华， 徐文祥， 丁晓丽   

  1. 安徽工业大学材料科学与工程学院，安徽 马鞍山 243002
  • 收稿日期:2018-05-15 修回日期:2018-07-03 出版日期:2019-04-22 发布日期:2019-04-18
  • 通讯作者: 斯庭智 tzsiahut@163.com
  • 基金资助:
    国家自然科学青年基金

Phase evolution and corrosion resistance of MgxTiAlFeNiCr (x=0.6~2.0) high-entropy alloys

Tingzhi SI*, Qinghua LIU, Wenxiang XU, Xiaoli DING   

  1. School of Materials Science and Engineering, Anhui University of Technology, Ma?anshan, Anhui 243002, China
  • Received:2018-05-15 Revised:2018-07-03 Online:2019-04-22 Published:2019-04-18

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摘要： 通过机械合金化方法制备了轻质MgxTiAlFeNiCr(x=0.6?2.0)高熵合金，研究了Mg含量、热力学参数、合金相结构间的关系。结果表明，Mg在体心立方(BCC)相中的固溶度较大，x=0.6?1.4、合金的热力学参数原子半径错配度?=8.68%?9.77%、混合熵ΔSmix为14.78?14.82 J/(mol?K)，混合焓ΔHmix为–14.13?–6.76 kJ/mol时，合金为单相体心立方结构(BCC1)。x=1.6~1.8, ?=10.0%?10.1%, ΔSmix=14.65?14.74 J/(mol?K), ΔHmix=–5.40?–4.19 kJ/mol时，合金由两种体心立方结构BCC1和BCC2组成。BCC2相比BCC1相的Mg含量更高，两相界面为半共格关系。MgxTiAlFeNiCr合金在3.5wt% NaCl溶液中具有良好的耐腐蚀性能。但随Mg含量增加，合金的耐蚀性下降。

关键词: 高熵合金, 相结构, 热力学, 耐蚀性

Abstract: The novel low density MgxTiAlFeNiCr (x=0.6~2.0) high-entropy alloys were prepared by mechanical alloying, the relation of Mg content, thermodynamic parameter and phase structure was researched. The results showed that the prepared high-entropy alloy powders were approximately spherical particles with a diameter about 3 μm. The measurements of X-ray diffraction (XRD) and analyses of energy-dispersive X-ray spectrometry (EDS) revealed that Mg had a high solid solubility in BCC (body center cubic) lattice. The results of thermodynamic calculation showed that the alloys (x=0.6~1.4) had a single BCC1 phase when 8.68%≤δ≤9.77% (δ was atomic radii mismatches), 14.78 J/(mol?K)≤ΔSmix≤14.82 J/(mol?K) (ΔSmix was mixing entropy) and –14.13 kJ/mol≤ΔHmix≤–6.76 kJ/mol (ΔHmix was mixing enthalpy). However, the alloys (x=1.6~1.8) consisted of BCC1 and BCC2 phases when 10.0%≤δ≤10.1%, 14.65 J/(mol?K)≤ΔSmix≤14.74 J/(mol?K) and –5.40 kJ/mol≤ΔHmix≤–4.19 kJ/mol. When x≥2.0, Mg content exceeded the solid solubility of Mg in BCC1 and BCC2 lattices. As a result, Mg2.0TiAlFeNiCr alloy contained the main phases BCC1 and BCC2 and the minor phases Mg and intermetallic compound. The lattice constant (a) of BCC1 and BCC2 were determined respectively to be 0.289 and 0.291 nm by the XRD measurement and high resolution transmission electron microscope (HRTEM) analysis. For BCC1 phase, Fe acted as a solvent element whereas Mg, Ti, Al, Ni and Cr behaved like solute elements. For BCC2, however, Cr acted as a solvent element whereas Mg, Ti, Al, Fe and Ni behaved like solute elements. Compared with BCC1, high Mg content was achieved in BCC2 phase. Moreover, BCC1 and BCC2 displayed a semicoherent interface. The MgxTiAlFeNiCr (x=0.6~2.0) high-entropy alloys exhibited a good corrosion resistance in 3.5wt% NaCl solution. But the corrosion resistance decreased with the increasing of Mg in the alloys.

Key words: High-entropy alloys, Phase structure, Thermodynamics, Corrosion resistance