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过程工程学报 ›› 2019, Vol. 19 ›› Issue (6): 1143-1152.DOI: 10.12034/j.issn.1009-606X.219127

• 过程与工艺 • 上一篇    下一篇

苯酚浓度对亲油疏水型滤材聚结性能的影响

郭 骥1,2， 姬忠礼1,2*   

  1. 1. 中国石油大学(北京)机械与储运工程学院，北京102249 2. 中国石油大学(北京)过程流体过滤与分离技术北京市重点实验室，北京102249
  • 收稿日期:2019-01-29 修回日期:2019-04-03 出版日期:2019-12-22 发布日期:2019-12-22
  • 通讯作者: 姬忠礼 jizhongli63@vip.sina.com
  • 基金资助:
    天然气净化用气液聚结滤芯过滤分离机理研究

Influence of phenol concentration on coalescence performance of an oleophilic?hydrophobic filter material

Ji GUO1,2, Zhongli JI1,2*   

  1. 1. Department of Mechanical and Transportation Engineering, China University of Petroleum, Beijing 102249, China 2. Beijing Key Laboratory of Process Fluid Filtration and Separation, China University of Petroleum, Beijing 102249, China
  • Received:2019-01-29 Revised:2019-04-03 Online:2019-12-22 Published:2019-12-22
  • Contact: JI Zhong-li jizhongli63@vip.sina.com
  • Supported by:
    Study on filtration and separation mechanism of gas-liquid coalescing filter element for natural gas purification

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摘要： 为探究油品中非烃化合物对滤材聚结性能的影响，在固定含水量1000?10?6(wt)的油水乳状液中添加不同浓度的苯酚，研究亲油疏水滤材的除水效率及过程压降。结果表明，实验过程中滤材的压降有3个阶段：油品对滤材的润湿及水膜初步形成、滤材中水膜形成并稳定、水珠脱落与聚结的动态平衡。随苯酚浓度增加，滤材从疏水态经过渡态逐渐转变为亲水态，苯酚与水摩尔比约为1:3.3时，疏水态向过渡态转变，苯酚与水摩尔比约为1:1.6时，过渡态向亲水态转变，C6H6O(H2O)2是苯酚?水团簇最稳定的结合方式。

关键词: 油水分离, 苯酚浓度, 亲水态, 疏水态, 过程压降, 苯酚水团簇

Abstract: In the fields of aerospace, refinery and hydraulic system, moisture in oil should be controlled within a certain range. Oil?water coalescing separator is an effective method to remove water from oil, but in some areas, the oil usually contains non-hydrocarbon components that affect filtration efficiency. In order to explore the influence of non-hydrocarbon compounds in oil on the coalescing properties of filter media, influence of phenol concentration on efficiency and pressure drop of oleophilic?hydrophobic filter material were studied experimentally by adding phenol of different concentrations to the emulsion of 1000?10?6(wt) water content. The results showed that the pressure drop of the filter material in this experiment had three stages: oil wetting filter material and preliminary formation of water films, water film reaching steady state, droplet shedding and coalescence reaching the dynamic balance. With the increase of phenol concentration, the hydrophobic state of the filter material gradually changed to hydrophilic state, the filter material had undergone three stages: hydrophobic state, transition state and hydrophilic state. When the molar ratio of phenol to water was about 1:3.3, the hydrophobic state changed into transition state, when the molar ratio of phenol to water was about 1:1.6, the transition state changed into hydrophilic state. C6H6O(H2O)2 was the most stable structure of phenol combined with water.

Key words: oil water separation, phenol concentration, hydrophobic state, hydrophilic state, process of pressure drop, phenol water cluster